The whole of EDEXCEL Chemistry Paper 2 or C2 in only 47 minutes. 9-1 GCSE Science Revision
Summary
TLDRIn this video, comprehensive topics relevant to the second LXL chemistry exam are covered. It begins with an overview of the periodic table, detailing various groups such as alkali metals and noble gases. Key reactions, such as displacement reactions, are explained using examples and practical demonstrations. The video delves into the concepts of exothermic and endothermic reactions, factors affecting the rate of reaction, and the principles of hydrocarbons, including combustion processes. The significance of global warming and pollution, along with the effects of chemical reactions on the environment, are highlighted. Additionally, tests for identifying ions, different types of hydrocarbons, and the polymerization processes are discussed, along with the impact of nanotechnology. The video aims to aid students in their revision for their exams and offers encouragement for their upcoming tests.
Takeaways
- ๐ Comprehensive exam guide for chemistry
- ๐งช Overview of periodic table groups
- โ๏ธ Understanding of halogens' reactivity
- ๐ฅ Explanation of combustion types
- ๐ Discussion on environmental impacts
- ๐ Factors affecting the rate of reaction
- ๐ก๏ธ Endothermic vs exothermic reactions
- ๐ฌ Identifying ions through tests
- ๐ Importance of hydrocarbons and their combustion
- ๐งฌ Insights into nanotechnology and its applications
Timeline
- 00:00:00 - 00:05:00
The video is a comprehensive guide for students preparing for their second LXL chemistry exam, covering essential topics including the periodic table, reactivity of metals, chemical reactions, and rates of reaction. A free guide is available on the host's website for additional support.
- 00:05:00 - 00:10:00
The periodic table is divided into groups with distinct properties. Group 1 contains alkaline metals, Group 2 contains alkaline earth metals, Group 7 has halogens, while Group 8 consists of noble gases. Noble gases are unreactive due to having a full outer electron shell, leading to various practical applications.
- 00:10:00 - 00:15:00
Halogens, which include chlorine and fluorine, are highly reactive nonmetals that often exist as diatomic molecules. They gain one electron during reactions and can displace less reactive elements. The reactions between halogens and metals produce salts, such as sodium chloride, and are important for sterilizing agents.
- 00:15:00 - 00:20:00
Alkaline metals are known for their violent reactions with water, often producing a lot of heat and hydrogen gas. These metals must be stored in oil to prevent reactions with water or oxygen in the air. When reacting with water, they form metal hydroxides, contributing to their classification as alkaline.
- 00:20:00 - 00:25:00
The rate of reaction can be influenced by the concentration of reactants, surface area, and temperature. Tracking changes in mass or volume during reactions can help quantify the rates. Measuring techniques such as using a measuring cylinder or tracking gas production are essential in experiments to understand reaction rates.
- 00:25:00 - 00:30:00
In chemical reactions, different factors such as temperature and concentration affect how quickly and efficiently particles collide. Higher temperatures increase energy and movement, leading to more frequent successful collisions, therefore increasing the rate of reaction.
- 00:30:00 - 00:35:00
Catalysts lower the activation energy required for reactions and can significantly increase reaction rates by providing a better pathway for the reacting particles. The difference between endothermic and exothermic reactions relates to energy change, with endothermic reactions absorbing energy and exothermic reactions releasing it.
- 00:35:00 - 00:40:00
The process of fractional distillation is vital for separating mixtures like crude oil into useful hydrocarbons. Both complete and incomplete combustion processes lead to different products, with incomplete combustion resulting in toxic substances like carbon monoxide.
- 00:40:00 - 00:47:47
Global warming and air pollution from greenhouse gases such as carbon dioxide and sulfur dioxide have significant environmental impacts. Understanding the composition changes in the atmosphere over time and the consequences of anthropogenic activities is critical for effective environmental management.
Mind Map
Video Q&A
What does the periodic table categorize?
The periodic table categorizes elements into groups such as alkaline metals, alkaline earth metals, halogens, noble gases, and transition metals.
What do halogens want to do when they react?
Halogens want to gain one electron when they react, resulting in the formation of minus one ions.
How does temperature affect the rate of reaction?
Higher temperatures increase the rate of reaction by providing particles with more energy, leading to more frequent successful collisions.
What are hydrocarbons and how are they separated?
Hydrocarbons are compounds made of only hydrogen and carbon. They are separated through fractional distillation.
What is the difference between complete and incomplete combustion?
Complete combustion occurs with ample oxygen, producing water and carbon dioxide, while incomplete combustion occurs with limited oxygen, producing carbon monoxide and soot.
What causes global warming?
Global warming is primarily caused by increased levels of carbon dioxide in the atmosphere due to human activities.
What is a catalyst?
A catalyst is a substance that speeds up a chemical reaction by lowering the activation energy required for the reaction.
What happens during an endothermic reaction?
An endothermic reaction absorbs energy, causing a decrease in temperature.
What do alcohols end with?
Alcohols end with the suffix 'ol' and contain an -O-H functional group.
What is nanotechnology?
Nanotechnology involves rearranging atoms at a small scale to create materials with different properties and potentially various applications.
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- 00:00:00- Hello lovely kittens in this video I cover everything
- 00:00:02you need for your second LXL chemistry exam,
- 00:00:06I'm gonna go over a summary of everything,
- 00:00:08But if you want to make sure you don't miss anything
- 00:00:10you want loads and loads of quickfire questions,
- 00:00:13all the bits you need to learn for chemistry,
- 00:00:15all the irons, the activity series,
- 00:00:17what goes with what,
- 00:00:18you can get that in your free guide
- 00:00:19which is over on my website,
- 00:00:22there are loads of practicals
- 00:00:23in this one guys so remember to pay attention to those,
- 00:00:26loads and loads of videos if there's anything
- 00:00:28you need just ask.
- 00:00:29(cheerful music)
- 00:00:35This beautifully colored periodic table
- 00:00:36is because there are lots of different groups,
- 00:00:38lots of different categories on the periodic table.
- 00:00:42Number one also known as alkaline metals,
- 00:00:46group number two other alkaline earth metals
- 00:00:48or alkali metals,
- 00:00:50group seven are the halogens,
- 00:00:54and group eight are the noble gases,
- 00:00:57the big chunk in the middle are the transition metals.
- 00:01:01The group right on the far right-hand side
- 00:01:03are group eight or group zero,
- 00:01:04these are the noble gases,
- 00:01:07they have a full outer shell,
- 00:01:14and because they have a full outer shell they don't want
- 00:01:17to gain or lose any electrons which means
- 00:01:19they're really, really unreactive,
- 00:01:23and because they're unreactive,
- 00:01:24they actually have quite a lot of uses,
- 00:01:27helium used in balloons,
- 00:01:30and they are also used in neon lights,
- 00:01:34as you can see here the amazing city of Osaka.
- 00:01:38Moving over one group to group seven we have the halogens,
- 00:01:42we are still in the nonmetals,
- 00:01:46and these are gonna go around as diatonic molecules,
- 00:01:50which means their formula is going
- 00:01:53to be for a chlorine gas Cl2,
- 00:01:55fluorine gas F2,
- 00:01:56bromine gas Br2,
- 00:01:58they're gonna go around together in pairs,
- 00:02:01because they only want to gain one electron
- 00:02:03a nice easy way for them to do that
- 00:02:05is sharing an electron with something else that is the same,
- 00:02:08so fluorine here can easily gain an extra electron
- 00:02:11by sharing it with another florine.
- 00:02:14They are highly reactive because they
- 00:02:16only want to gain one electron.
- 00:02:22And the most reactive ones are going to be at the top.
- 00:02:36Boiling point is going to change as we move down the group,
- 00:02:40so things that have low boiling point or a low melting
- 00:02:43point are gonna be at the top,
- 00:02:46High boiling point or high melting point
- 00:02:48are going to be at the bottom.
- 00:02:50When they react there gonna gain an electron.
- 00:02:58Meaning they're going to form minus one ions.
- 00:03:04And gaining an electron is reduction.
- 00:03:12They're going to react violently and rapidly with group
- 00:03:15one medals because group one metals want
- 00:03:16to lose one electron,
- 00:03:19for example sodium which is a soft gray metal,
- 00:03:22while react very violently with chlorine
- 00:03:25which is a yellow gas,
- 00:03:26to form sodium cloride which is a white powder or salt.
- 00:03:31A more reactive element will displace
- 00:03:33a less reactive element,
- 00:03:35so here we have sodium iodide reacting with bromine,
- 00:03:39iodine is here below bromine on
- 00:03:42the periodic table so bromine is more reactive,
- 00:03:45so we will displace iodine in the compound
- 00:03:49forming sodium bromide and iodine.
- 00:03:52Whereas if you try and react bromine gas
- 00:03:53with sodium chloride,
- 00:03:55chlorine is higher than bromine on the periodic table,
- 00:03:58so it's more reactive,
- 00:03:59you are gonna get no reaction,
- 00:04:01because bromine cannot displace chlorine out of this,
- 00:04:04these are commonly known as displacement reactions.
- 00:04:17The halogens are mostly used for sterilizing things,
- 00:04:20for example chlorine,
- 00:04:22you are commonly going to know that as from swimming pools.
- 00:04:27Halogens want to gain one electron,
- 00:04:29so the most reactive ones at the top,
- 00:04:31that's where there's least shielding between
- 00:04:34the electron they want to gain and the nucleus.
- 00:04:38Alkaline metals react very violently with water,
- 00:04:39and this is where your gonna see some flames coming from,
- 00:04:42Some different colors coming from.
- 00:04:45This is one of the things we use to make
- 00:04:46the different colors in fireworks,
- 00:04:48so the lovely lovely lilac flame of potassium
- 00:04:51we can use in fireworks.
- 00:04:54If you've seen these in schools these
- 00:04:55are soft gray metals which are easily cutable,
- 00:04:58they need to be kept in oil so it doesn't
- 00:05:00react with oxygen or with water in the air,
- 00:05:03because it's a very, very violent reaction.
- 00:05:07When the metal reacts with oxygen
- 00:05:08we're gonna get a metal oxide,
- 00:05:09which if you've seen these in school when
- 00:05:11it was cut it was shiny,
- 00:05:13but it soon started to dull,
- 00:05:15the dullness is the metal oxide,
- 00:05:17the metal plus water is going to form a metal hydroxide,
- 00:05:19this gives it its name,
- 00:05:21it's alkaline metal because the metal hydroxide
- 00:05:24is going to be alkaline,
- 00:05:26you can see that by the change in indicator.
- 00:05:29If that's what your teacher did.
- 00:05:31And you will also notice this is a very exothermic reaction,
- 00:05:34it releases a lot of heat,
- 00:05:37it also releases hydrogen gas.
- 00:05:41That's what the fizzing was.
- 00:05:44The reactivity is most reactive at the bottom.
- 00:05:52And least reactive at the top.
- 00:06:00Things at the bottom are going to have
- 00:06:02a low melting point or boiling point,
- 00:06:05and a higher melting point or boiling point at the top.
- 00:06:10Alkaline metals want to lose an electron,
- 00:06:12and the ones at the bottom are the most reactive
- 00:06:14because there's more shielding between the
- 00:06:16the electrolyte they want to use and
- 00:06:18the positive nucleus in the middle.
- 00:06:22They are arranged in different ways,
- 00:06:24you can follow a reaction,
- 00:06:25for example you can look at the loss of mass,
- 00:06:28this would be good if you are adding something solid,
- 00:06:31like marble chips into a liquid,
- 00:06:35and you knew that the gas was going to be produced,
- 00:06:38the gas will just go up here through
- 00:06:40the cotton wool and out,
- 00:06:42and the mass will go down.
- 00:06:45It will also for the same reaction if you have a solid,
- 00:06:48and you're adding it into liquid,
- 00:06:49and a gas was being produced,
- 00:06:51you could collect the gas either in a measuring syringe,
- 00:06:54or an inverted measuring cylinder.
- 00:06:59When we are measuring the rate of a reaction
- 00:07:00we need to look carefully at the units used.
- 00:07:04For example here we have volume,
- 00:07:07in centimeters cubed over time in minutes,
- 00:07:10so here it would be centimeters cubed per minute,
- 00:07:16and the second one we have time in seconds
- 00:07:20and mass in grams.
- 00:07:22So this would be grams per second.
- 00:07:25In the first graph it is volume
- 00:07:27of carbon dioxide being produced,
- 00:07:29so you can see that is going up,
- 00:07:32and in the second graph is mass being lost,
- 00:07:35so you can see that is going down.
- 00:07:38If you want to find the rate at a particular point,
- 00:07:41say two minutes or five minutes,
- 00:07:43you need to draw a tangent which is a straight line,
- 00:07:47that touches the curve just at that point,
- 00:07:50not at any other point,
- 00:07:51just at the point you're interested in,
- 00:07:53then you need to work out the gradient of that line,
- 00:07:58to work out the gradient you need to draw a triangle,
- 00:08:01the bigger triangle the better,
- 00:08:03and we need to work out the change
- 00:08:04up divided by the change in across,
- 00:08:07and your units,
- 00:08:08you need to take from the graph.
- 00:08:12You can compare the rates of reaction
- 00:08:13at different points in a reaction,
- 00:08:16for example at the start of this reaction,
- 00:08:19our line, our tangent is very, very steep,
- 00:08:22whereas later on in the reaction at
- 00:08:24a different point our tangent is very shallow,
- 00:08:27different rates of reaction at different points.
- 00:08:32We can follow the route of reaction by looking
- 00:08:34at the color change taking place in the reaction,
- 00:08:36or how it changes from clear colorless
- 00:08:40to opaque where we can't see a cross underneath any more,
- 00:08:44this reaction is between sodium iodosulfate
- 00:08:46and hydrochloric acid,
- 00:08:48and you need to be really, really careful with this one,
- 00:08:50careful that when you're doing these you're
- 00:08:51constantly washing things out
- 00:08:53so you're not contaminating things,
- 00:08:55careful you don't take it above 60 degrees,
- 00:08:57because then nasty gases will start to come off at the end,
- 00:09:01be careful that you don't get it on your hands,
- 00:09:03because it's gonna start to irritate your hands,
- 00:09:06so this is where health and safety is a really big concern.
- 00:09:09You can see as the reaction is going on,
- 00:09:12the cross which was visible at the beginning
- 00:09:14is becoming less and less visible.
- 00:09:17You need to make sure that the same person always measures
- 00:09:20the rate of reaction here so differences
- 00:09:23in people's eyes don't mean that the differences
- 00:09:26in the time that the cross disappears
- 00:09:29could affect the results.
- 00:09:33One way that we can collect gas,
- 00:09:35is by using an inverted measuring cylinder
- 00:09:38and putting a delivery tube through there,
- 00:09:41one of the things you need to be careful about,
- 00:09:42is this gas in here that is already
- 00:09:45in the measuring cylinder before you start the experiment,
- 00:09:49that is one place that errors can be introduced.
- 00:09:54The gas is going to move from the conical flask through
- 00:09:56the delivery tube and into the measuring cylinder,
- 00:10:00and it's gonna be collected and we can measure it.
- 00:10:02Adding in large marble chips now you can
- 00:10:06see that the bubbles are starting to collect,
- 00:10:08in the measuring cylinder,
- 00:10:11in this not only can you get errors,
- 00:10:12because there's going to be gas in
- 00:10:14the measuring cylinder before you start,
- 00:10:16but there is also going to be some gas last
- 00:10:19before you manage to get the bung on.
- 00:10:25Adding in powdered calcium carbonate now,
- 00:10:29you'll notice that the rate of reaction,
- 00:10:30the bubbles are produced much, much faster,
- 00:10:33the measuring cylinder fills up very quickly.
- 00:10:39When we have particles moving around at
- 00:10:40a low temperature they are moving
- 00:10:42slowly with not much energy,
- 00:10:45when two collide they hit each other and have a reaction,
- 00:10:47but sometimes they are going to collide
- 00:10:49and is not going to be a reaction.
- 00:10:51When particles move around with high temperature
- 00:10:54at high-speed with lots of energy,
- 00:10:56when things collide you are going to get
- 00:10:58a lot of reactions taking place,
- 00:11:02rate of reaction is going to be affected by temperature,
- 00:11:04here I've put sugar cubes into hot water and cold water,
- 00:11:09and you can see the sugar cubes in hot water
- 00:11:11dissolved much much faster than
- 00:11:13the sugar cubes in cold water.
- 00:11:20For the rate of reaction we can say that
- 00:11:22the higher the temperature,
- 00:11:32the faster the rate of reaction will be,
- 00:11:49this is because the particles have more energy.
- 00:12:05So they can move around faster.
- 00:12:15And this will lead to more frequent successful collisions.
- 00:12:34When we have a lump of something it has less surface
- 00:12:37area so there's less space to react,
- 00:12:39here the blue dots whatever that is can only
- 00:12:41react with the pink dots on the outside,
- 00:12:44the purple dots on the inside or exactly
- 00:12:46the same thing they are just not available to react,
- 00:12:48whereas here the pink dots are all spread out
- 00:12:51in a powder format so they're all available to react.
- 00:12:55This is really confusing because the lump
- 00:12:57is larger than the powder,
- 00:13:00but assuming we have exactly the same mass,
- 00:13:02the powder has more surface area than the lump,
- 00:13:06so more particles are available to react.
- 00:13:09Here I have two identically sized blobs of glue,
- 00:13:12and one spread out,
- 00:13:15and one I haven't spread out,
- 00:13:17I've just left it as a blob,
- 00:13:18and you see the one that's spread out,
- 00:13:19the one that has a large surface area has
- 00:13:22dries much, much faster than the one
- 00:13:24I've just left in a big blob.
- 00:13:28I have a What's App group of all my YouTube friends
- 00:13:31and they are super, super jealous when I told
- 00:13:33I was making a video of glue drying.
- 00:13:40We can say that the larger the surface area.
- 00:13:54The faster the rate of reaction.
- 00:14:07This is because.
- 00:14:15There are more particles available to react.
- 00:14:26Leading to,
- 00:14:34more successful collisions.
- 00:14:41If we have things at a high pressure or
- 00:14:43a high concentration there are more of them,
- 00:14:45which means they are much more likely
- 00:14:47to bump into each other and react,
- 00:14:48whereas at a low concentration they're not
- 00:14:51very likely to bump into each other and react.
- 00:14:54We can say that the higher the pressure or concentration.
- 00:15:10The faster the rate of reaction will be.
- 00:15:25This is because there are more particles.
- 00:15:40In a fixed volume.
- 00:15:50So there is a higher chance,
- 00:15:59Of a successful collision.
- 00:16:07When we have a catalyst it's something that makes
- 00:16:10a reaction easier to happen,
- 00:16:12it lowers the activation energy,
- 00:16:13so for example this catalyst fixes
- 00:16:15one of the reactants in place,
- 00:16:17so it's easier for the other reactant to find it,
- 00:16:20over this side they are both randomly
- 00:16:22wandering around in the dark,
- 00:16:23and it's quite hard to find people when
- 00:16:24you're wandering around in the dark,
- 00:16:28whenever we have a reaction there's an activation energy,
- 00:16:32instead of just going straight from
- 00:16:33the reaction to the product,
- 00:16:34there's this hump it has to get over,
- 00:16:37and this bit here,
- 00:16:39this difference is the activation energy.
- 00:16:47However what a catalyst does is it lowers
- 00:16:49the activation energy,
- 00:16:52so it's easier for the reaction to take place.
- 00:17:01So the reaction is more likely to happen
- 00:17:03because there's less of a hump for it to get over.
- 00:17:07An endothermic reaction feels like it gets colder,
- 00:17:12whereas an exothermic reaction feels like it get hotter.
- 00:17:18Another way of saying gets colder is to take heat in,
- 00:17:21another way to get hotter is to give out.
- 00:17:25Now we can make this slightly more sophisticated
- 00:17:26by replacing the word heat with the word energy.
- 00:17:35So now a sophisticated answer is that
- 00:17:36an endothermic reaction takes energy in
- 00:17:39and an exothermic reaction gives energy out.
- 00:17:43During an endothermic reaction energy is going
- 00:17:46to get taken in so we have our reactants down here.
- 00:17:51Energy gets taken in so our products up here.
- 00:18:00So we can say that the energy of the products,
- 00:18:11is higher,
- 00:18:16than the energy,
- 00:18:23reactants.
- 00:18:26During an exothermic reaction energy reaction
- 00:18:28is given out, so reactants.
- 00:18:34Energy is given out,
- 00:18:36so our products are going to be down here,
- 00:18:40which means our products,
- 00:19:00have lower energy than the reactants.
- 00:19:03For example an endothermic reaction would be electrolysis.
- 00:19:11An exothermic reaction would be burning.
- 00:19:15Or neutralization.
- 00:19:22You need to be able to calculate the energy
- 00:19:24change when a reaction takes place,
- 00:19:26remembering a bonds energy breaking takes energy in,
- 00:19:28and bond making gives energy out.
- 00:19:31So burning hydrogen in oxygen will give out water,
- 00:19:34calculate the energy change for this reaction.
- 00:19:36The first thing we need to do is write a balanced equation.
- 00:19:39Hydrogen plus oxygen
- 00:19:45gives water,
- 00:19:47we need to put the two there to balance out the oxygens,
- 00:19:50and two there to balance out the hydrogens,
- 00:19:53draw everything we have,
- 00:19:56so we have hydrogen and we have two of them,
- 00:20:00so I'm gonna draw that twice,
- 00:20:02plus oxygen turns into
- 00:20:09water.
- 00:20:14And while the examiner will probably expect
- 00:20:16you to be able to work out the formula,
- 00:20:18balance the equation and draw them by yourself,
- 00:20:19they would not expect you to write all the bonds in,
- 00:20:22the bond energies will be given to you in the exam,
- 00:20:26next we're going to list the type of bonds
- 00:20:27that we have and the number,
- 00:20:28so we have hydrogen hydrogen bonds,
- 00:20:31and we have one, two of those,
- 00:20:36we have an oxygen oxygen double bond,
- 00:20:38and we have just one double bond in there,
- 00:20:43we have oxygen hydrogen bond,
- 00:20:46and we have one, two, three, four of those,
- 00:20:53now we need to take that and multiply
- 00:20:55it by our bond energies,
- 00:20:56so two bonds for hydrogen,
- 00:20:58that's two times 436,
- 00:21:01one times 498,
- 00:21:05four time 464,
- 00:21:09we can do the maths and work out how much is on each side,
- 00:21:12adding those up,
- 00:21:13872 plus 498 gives us 1370,
- 00:21:19it's just 1856 on that side,
- 00:21:25now we need to do the energy of the reactants,
- 00:21:26minus the energy of the products,
- 00:21:27so 1370 minus 1856,
- 00:21:31giving us minus 486 kilojoules per mole.
- 00:21:40In this type of equation if you got the symbol wrong
- 00:21:42you'd probably only lose one mark,
- 00:21:45it having a negative sign in front of
- 00:21:47the tells us it is exothermic.
- 00:21:52So any reaction that is burning you can
- 00:21:54check yourself because it should always be exothermic.
- 00:21:58We can pretty much guarantee that a big calculation
- 00:21:59is going to come up on this paper,
- 00:22:01so it's worth practicing these really well,
- 00:22:04to help you I've written a book.
- 00:22:08A couple of key definitions you need to know,
- 00:22:10A hydrocarbon is a compound
- 00:22:17that is made up of hydrogen
- 00:22:25and carbon only and nothing else.
- 00:22:31Crude oil,
- 00:22:37is a mixture of different length
- 00:22:47hydrocarbons.
- 00:22:53To separate out the mixture of crude oil,
- 00:22:56we need to use fractional distillation.
- 00:22:59Crude oil goes in gets heated up until it is a gas,
- 00:23:04then it goes into a condensing column,
- 00:23:07all of the really, really long chain hydrocarbons
- 00:23:11which don't evaporate come off here as a residue,
- 00:23:14and we can use that,
- 00:23:15the bitumen,
- 00:23:16we can use that for making roads.
- 00:23:19It is very, very hot at the bottom,
- 00:23:21and as we move up the condensing tower
- 00:23:24the temperature goes down,
- 00:23:26at each different point,
- 00:23:29different length hydrocarbons are going to come off,
- 00:23:32so we have gases at the top,
- 00:23:34petrol, naphtha and kerosene which is fuel for planes,
- 00:23:39diesel and then fuel for boats.
- 00:23:43Short hydrocarbons are going to come off at the top,
- 00:23:45and long hydrocarbons are gonna come off at the bottom.
- 00:23:49Things at the top are gonna be really, really flammable,
- 00:23:52things at the bottom aren't going
- 00:23:53to be really, really flammable,
- 00:23:55things at the bottom are going to be really viscous,
- 00:23:57whereas things at the top aren't going to be viscous.
- 00:24:02The long hydrocarbons that come out
- 00:24:05of fractional distillation,
- 00:24:05aren't always the most useful ones,
- 00:24:08we get large amounts of long ones which aren't very useful,
- 00:24:11but we don't get very many short ones which
- 00:24:12we need because they are useful,
- 00:24:15so we can crack the long ones using heat and a catalyst,
- 00:24:20and this is going to give us short alkanes
- 00:24:22which we want and alkenes.
- 00:24:27The complete combustion of hydrocarbon involves
- 00:24:30lots of oxygen,
- 00:24:32that is your roaring blue flame on a Bunsen burner,
- 00:24:36this is gonna be hydrocarbon plus oxygen,
- 00:24:39turning into water and carbon dioxide.
- 00:24:43Incomplete combustion as well as not enough oxygen,
- 00:24:46this is going to be your orange flame in the Bunsen burner,
- 00:24:49this is much more problematic,
- 00:24:50because as well as the water and carbon dioxide,
- 00:24:52we're gonna get carbon monoxide,
- 00:24:53which is highly toxic,
- 00:24:54your white blood cells prefer it to oxygen,
- 00:24:59so you will actually suffocate to death
- 00:25:02generally in your sleep,
- 00:25:03and carbon which is black suit,
- 00:25:06which gets everywhere.
- 00:25:10There are three main greenhouse gases
- 00:25:12with the biggest culprit being carbon dioxide,
- 00:25:14and to a much smaller extent water vapor and methane.
- 00:25:19The bonds in carbon dioxide are really,
- 00:25:21really good at absorbing infrared or heat radiation,
- 00:25:25which traps it inside our atmosphere and warms the planet.
- 00:25:30Which means that when heat light energy
- 00:25:34from the sun comes to us,
- 00:25:36it will be reflected back by the earth,
- 00:25:39and normally this would go straight back out into space,
- 00:25:45but it's not,
- 00:25:46it's being trapped by the greenhouse gases,
- 00:25:50by the carbon dioxide,
- 00:25:51by the methane,
- 00:25:53which means it stays in our atmosphere heating it up.
- 00:25:59We can see a gradual increase in the levels
- 00:26:01of carbon dioxide which has taken up speed in recent years,
- 00:26:06and there are lots of things that humans do
- 00:26:08that have a massive amount to do with the levels
- 00:26:10of carbon dioxide in the atmosphere,
- 00:26:13global warming is a slightly confusing term,
- 00:26:15because not everywhere is getting hotter,
- 00:26:17where we do have places getting hotter,
- 00:26:19where deserts, countries, farmland is drying out completely,
- 00:26:25and the ice poles are getting hotter as well,
- 00:26:27which is really, really bad for the polar bears.
- 00:26:30Because they live on these blocks of ice,
- 00:26:33they hunt in the water,
- 00:26:35and when they need a break from swimming and hunting,
- 00:26:37they jump onto the blocks of ice and have a rest,
- 00:26:40the bottom of these blocks of ice are melting,
- 00:26:42there is nowhere for the polar bears to have a rest,
- 00:26:44so loads and loads of polar bears are drowning,
- 00:26:47and while the ice caps are melting,
- 00:26:49it means we are seeing increased levels
- 00:26:49of flooding in other places.
- 00:26:53As the sea levels go up certain places on
- 00:26:56the coast are going to start to end up underwater,
- 00:27:00while Australia is having it's hottest Christmases ever,
- 00:27:04us here in the UK are having our coldest Christmases ever,
- 00:27:06with unprecedented levels of snow.
- 00:27:09And the climate change doesn't just fit people,
- 00:27:11it affects animals and plants as well,
- 00:27:14as the temperature changes the top of
- 00:27:16the mountain which perhaps used to be under snow,
- 00:27:18is now available for habitation by new animals and plants,
- 00:27:23now say you have a little house here,
- 00:27:25and you knew it was protected from certain types of animals,
- 00:27:28because it was too cold or too warm for them there,
- 00:27:31with the changing climate,
- 00:27:33animals are moving up and down slopes,
- 00:27:35their habitats are changing as the temperature changes
- 00:27:37and as the location of their food source changes.
- 00:27:41Your carbon footprint is how much carbon
- 00:27:44your daily activities contribute to the atmosphere,
- 00:27:48this can be impacted by things such as
- 00:27:50whether you decide to drive or whether
- 00:27:52you walk to your location,
- 00:27:54and whether you decide to eat food that is grown locally
- 00:27:56or food that has had to travel a long distance.
- 00:28:00Lots of human activities contribute to
- 00:28:02the production of carbon dioxide.
- 00:28:05Burning fossil fuels for use as electricity,
- 00:28:08deforestation cutting down trees,
- 00:28:10so that the trees can't take up carbon dioxide
- 00:28:12from the atmosphere any more,
- 00:28:14and our reliance on petrol cars.
- 00:28:18The predictions for the levels of carbon dioxide
- 00:28:20in our atmosphere is that they are just going to increase,
- 00:28:23and global warming is going to increase as well,
- 00:28:26unless we as a population decide to do something about it.
- 00:28:32One of the major pollutants is sulfur dioxide,
- 00:28:34when this goes up into the atmosphere
- 00:28:35it dissolves in the clouds,
- 00:28:37it is gonna come back down as acid rain.
- 00:28:40This is going to have an effect on a wide range of things,
- 00:28:42it is gonna have,
- 00:28:43animals that come into contact with it,
- 00:28:45if a lake or ocean or pond becomes too acidic,
- 00:28:49that's gonna start to kill the fish and the plants in there,
- 00:28:52plants are not going to appreciate having
- 00:28:53acid rained on them,
- 00:28:55so they are going to die,
- 00:28:55and it's also going to destroy limestone statues,
- 00:28:58which are going to dissolve in acid rain.
- 00:29:02Too much carbon in the air is gonna lead
- 00:29:04to larger levels of smog and global dimming,
- 00:29:08this is particularly prevalent in developing countries,
- 00:29:10when I was in Beijing it was really hard
- 00:29:12to see out the window because it was so smoggy.
- 00:29:17Water vapor is going to contribute To
- 00:29:18the warming of the planet,
- 00:29:20carbon monoxide is a toxic gas,
- 00:29:22and nitrogen oxides are going to contribute
- 00:29:24to both smog and acid rain.
- 00:29:28The air we breathe is made up of lots of different gases,
- 00:29:31predominantly nitrogen gas with about 20, 21 percent oxygen
- 00:29:35and then lots of other gases including
- 00:29:37a small amount of carbon dioxide.
- 00:29:41This is very different to the early atmosphere
- 00:29:43which was mainly formed by things coming out of volcanoes.
- 00:29:48So we have a large amount of ammonia,
- 00:29:53methane,
- 00:29:57water vapor in the air,
- 00:30:00carbon dioxide,
- 00:30:06this would have been a pretty unpleasant place to be,
- 00:30:09ammonia smells like hair dye
- 00:30:12or like really, really old baby nappies,
- 00:30:15and methane smells like farts,
- 00:30:17so the early atmosphere the early Earth would
- 00:30:19have smelled like farts and week-old baby nappies.
- 00:30:23The level of water vapor in the atmosphere
- 00:30:25decreased as it rained,
- 00:30:27which made the oceans,
- 00:30:29the levels of carbon dioxide decreased as
- 00:30:32the carbon dioxide dissolved in the newly formed oceans,
- 00:30:36it turned into fossils became locked up in rocks,
- 00:30:38and photosynthesis started to take place.
- 00:30:42The evolution of green plants,
- 00:30:44oxygen started to increase as photosynthesis
- 00:30:47was taking place.
- 00:30:50Well done you little superstars fantastic work,
- 00:30:52the rest of this video is for chemistry,
- 00:30:54so some of you can go and have a rest now,
- 00:30:56some of you still have a bit more work to do.
- 00:31:00I love flame tests,
- 00:31:01they are so, so pretty,
- 00:31:03you need to know that lithium will burn with
- 00:31:05a crimson flame,
- 00:31:06sodium will burn with a yellow flame,
- 00:31:08potassium will burn a lilac flame,
- 00:31:09calcium a red flame,
- 00:31:10barium with a green flame,
- 00:31:12even though it doesn't look green,
- 00:31:13and copper is going to burn with the blue green flame.
- 00:31:20If you're going to use sodium hydroxide
- 00:31:21to test for your positive ions,
- 00:31:23we need to look at the ionic equations,
- 00:31:25and we need to look at the precipitates.
- 00:31:28Testing for aluminum in sodium hydroxide is going
- 00:31:30to give you a white precipitate which
- 00:31:32is then going to dissolve,
- 00:31:34testing for calcium with sodium hydroxide,
- 00:31:36is just going to give you a white precipitate
- 00:31:37which will not dissolve,
- 00:31:39testing for magnesium with sodium hydroxide
- 00:31:41will give you a white precipitate,
- 00:31:43so in this circumstance you would need another
- 00:31:45test to differentiate between calcium and magnesium.
- 00:31:49Copper ions will give you a light blue precipitate,
- 00:31:52iron two ions will give you a gray green precipitate,
- 00:31:55and iron three ions will give you an orange precipitate.
- 00:31:59For the ionic equations,
- 00:32:00we have our hydroxide ion and then our metal ions,
- 00:32:03and you are expected to know all of these,
- 00:32:05then you just need to make sure your number
- 00:32:07of negative hydroxide ions is equal
- 00:32:09to the number of positive ions.
- 00:32:12So aluminum is three positives,
- 00:32:14so it needs three negative ions to become neutral overall.
- 00:32:18Calcium is two positive so it needs
- 00:32:21two negative ions to become neutral overall.
- 00:32:22Magnesium OH2,
- 00:32:26calcium OH2,
- 00:32:28iron OH2,
- 00:32:30iron three OH3.
- 00:32:35If you want to test something for Carbonate ion,
- 00:32:38you need to add hydrochloric acid,
- 00:32:40set up a delivery tube so any gas evolved
- 00:32:43will be collected down into limewater,
- 00:32:45and if it's carbon dioxide the limewater will go cloudy.
- 00:32:50If you want to test a sample to see if
- 00:32:51it contains sulfate ions,
- 00:32:52you need to add hydrochloric acid you
- 00:32:54need to add barium chloride,
- 00:32:56and if it contains sulfate irons you will
- 00:32:58get a white precipitate formed.
- 00:33:02If you want to test for hyalite ions
- 00:33:04you can add silver nitrate,
- 00:33:05and chloride ions will give a white precipitate.
- 00:33:09Bromide ions will give a cream precipitate,
- 00:33:11and iodide irons will give a yellow precipitate,
- 00:33:13yellow but not as yellow as the walls of my lab used to be.
- 00:33:16Now this can sometimes be a very, very subtle difference,
- 00:33:18and the best way to do it is by comparing
- 00:33:20it with the other things.
- 00:33:23In some cases doing tests in class might
- 00:33:25not be as good as using an instrumental method.
- 00:33:29Instrumental methods can be faster,
- 00:33:30they can be more accurate and they are unbiased.
- 00:33:35Alkanes are hydrocarbons with single bonds only,
- 00:33:39and the general formula for them is Cn H2n+2,
- 00:33:47the first one with one carbon is methane,
- 00:33:51two carbons is ethane,
- 00:33:55three carbons is propane,
- 00:33:59and four carbons is butane.
- 00:34:03When we're drawing organic compounds,
- 00:34:04the important thing to remember is
- 00:34:06that hydrogen always makes one bond,
- 00:34:08and one bond only,
- 00:34:09and carbon always makes four bonds and four bonds only.
- 00:34:14So you can see when I've drawn them,
- 00:34:15eight of the hydrogens here,
- 00:34:18only ever makes one bond,
- 00:34:21whereas the carbons each make
- 00:34:23one, two, three, four bonds,
- 00:34:25one, two, three, four bonds,
- 00:34:27one, two, three, four bonds,
- 00:34:30and because these are alkanes they
- 00:34:32are only ever going to have single bonds,
- 00:34:35this line here represents a bond,
- 00:34:37and that is a pair of electrons,
- 00:34:39this is a covalent bond between these.
- 00:34:42You need to know the names and be able
- 00:34:44to recognize the pictures of these.
- 00:34:49And we can see the formula for these follows
- 00:34:51our general formula of Cn H2n+2.
- 00:34:56So methane has one carbon and four hydrogens,
- 00:35:00Ethane two carbons six hydrogens,
- 00:35:03propane three carbons eight hydrogens,
- 00:35:05and butane four carbons and 10 hydrogens.
- 00:35:10Alkanes have a double bond and are unsaturated,
- 00:35:12the general formula for them is Cn H2n,
- 00:35:18all of these are going to end in ene,
- 00:35:21so there is with two carbons ethene
- 00:35:25with three carbons,
- 00:35:28propene, with four carbons,
- 00:35:32butene, with five carbons,
- 00:35:37pentene.
- 00:35:38When we are drawing things in organic chemistry
- 00:35:40we need to remember that hydrogen always makes
- 00:35:42one bond and carbon always makes four bonds.
- 00:35:46So ethene down here,
- 00:35:47hydrogen is making one bond,
- 00:35:49and carbon is making one, two, three, four bonds.
- 00:35:53This second carbon is making one, two, three, four bonds.
- 00:35:57A bond is a pair of electrons that are covalently shared.
- 00:36:01So a bond can be used by more than one carbon or hydrogen
- 00:36:05when we're counting things.
- 00:36:07You need to be careful looking at these ones,
- 00:36:09one, two, three, four,
- 00:36:10it would be very easy to make a mistake,
- 00:36:12drawing some of the carbons in the middle here
- 00:36:16you need to know how to name,
- 00:36:17recognize and draw the first four alkenes.
- 00:36:22The formulas for these,
- 00:36:23ethene, C2H4,
- 00:36:25propene C3H6,
- 00:36:26butene C4H8,
- 00:36:28pentene C5H10.
- 00:36:32To make this slightly harder the examiners
- 00:36:34might throw in some isomers.
- 00:36:36So this double bond for butane doesn't need to be here,
- 00:36:39it could be here,
- 00:36:40and these are named differently.
- 00:36:44Here the double one is in carbon number one,
- 00:36:46so that is but-1-ene,
- 00:36:48here the double bond is an carbon number one too,
- 00:36:50so this is but-2-ene
- 00:36:52here the double bond is an carbon number one,
- 00:36:54so this is pen-1-ene,
- 00:36:56whereas here the double bond is an carbon number two,
- 00:36:59so this is pen-2-ene.
- 00:37:02You need to know how to test for alkenes,
- 00:37:04this also tests for double bonds on saturation.
- 00:37:07You can see alkenes have two Es in there ,
- 00:37:11it means they have double bonds.
- 00:37:14For this test we use Bromine water
- 00:37:16and it goes from orange to colorless,
- 00:37:18colorless is really important here,
- 00:37:20clear is not going to be enough to get you the marks,
- 00:37:23it has to be colorless.
- 00:37:27The complete combustion of a hydrocarbon
- 00:37:30involves lots of oxygen,
- 00:37:32that is your roaring blue flame on a Bunsen burner.
- 00:37:36This is gonna be hydrocarbon plus oxygen turns
- 00:37:38into water and carbon dioxide.
- 00:37:42Incomplete combustion is where there's not enough oxygen,
- 00:37:45this is going to be an orange flame in a Bunsen burner,
- 00:37:48this is much more problematic,
- 00:37:50because as well as the water and carbon dioxide,
- 00:37:52we're gonna get carbon monoxide,
- 00:37:53which is highly toxic,
- 00:37:56your white blood cells prefer it to oxygen,
- 00:37:58so you'll actually suffocate to death generally
- 00:38:01in your sleep,
- 00:38:03and carbon which is black suit,
- 00:38:05which gets everywhere.
- 00:38:09The word mono means one,
- 00:38:12and mer means bit,
- 00:38:16Poly means lots and mer mean bits.
- 00:38:23So we can say a monomer is one bit and
- 00:38:25a polymer is lots of bits that have all been put together.
- 00:38:30If you're going to have our monomer of the ethene,
- 00:38:32that will just become Polyethene.
- 00:38:37So you just put Poly in front of the name there,
- 00:38:40and if we want to take the drawing
- 00:38:41and turn it into a polymer,
- 00:38:43we need to take this double bond and break it,
- 00:38:47so that bond goes outside,
- 00:38:48we have a single one between our two carbons,
- 00:38:50that's the other half of the bond,
- 00:38:53drawing in our hydrogens,
- 00:38:57square brackets,
- 00:38:59you need to make sure your bond extends
- 00:39:00outside the square brackets,
- 00:39:03and a little n after it,
- 00:39:05and you need to have a big N in front of your monomer.
- 00:39:10If we want to have a polymer of propene,
- 00:39:12we're gonna turn that into polypropene,
- 00:39:14we need to draw it in a slightly different way
- 00:39:16to the way you may be used to drawing it,
- 00:39:18with our double bond here,
- 00:39:19and third carbon up here going round a corner.
- 00:39:23Exactly the same way,
- 00:39:25break one of the bonds,
- 00:39:26one left in the middle,
- 00:39:27the other bond goes outside,
- 00:39:29and then all of the other groups around hydrogen
- 00:39:31stay the same.
- 00:39:37Little n after it,
- 00:39:39big N in front of it.
- 00:39:42If they want to try to make this more complicated,
- 00:39:43make a change this CH3 group for
- 00:39:45a fluorine group or a bromine group,
- 00:39:48all you do there is exactly the same,
- 00:39:50just replace the fluorine group in the same place.
- 00:39:56When we polymerized something,
- 00:39:57and I'm gonna show you condensation polymerization,
- 00:40:00we add monomers together,
- 00:40:03in condensation polymerization,
- 00:40:04we're going to add these bits together here,
- 00:40:07and we are gonna lose a water molecule,
- 00:40:11for condensation polymerization,
- 00:40:11you can see we have two different functional groups here,
- 00:40:16the opposite ends of amino acids,
- 00:40:18which I have drawn here,
- 00:40:20and we have lost water as a small molecule.
- 00:40:24Condensation polymerization is where
- 00:40:25we lose a small molecule from the reaction,
- 00:40:27and it is usually water but not always.
- 00:40:32Thermosetting and and thermosoftening polymers
- 00:40:34have very, very different properties,
- 00:40:36and this is based on their structures.
- 00:40:39Both have long polymer chains in,
- 00:40:41the thermosetting have cross links,
- 00:40:44whereas thermosoftening don't have cross links.
- 00:40:47This means upon heating the thermosetting
- 00:40:50polymers can just slide past each other,
- 00:40:52whereas thermosetting polymers cannot
- 00:40:53slide past each other.
- 00:40:56Which means thermosetting polymers are going to burn,
- 00:41:00and thermosoftening polymers are going to melt.
- 00:41:06Here is the structure of DNA that I have sitting on my desk,
- 00:41:09and you can see there are two lines going through it,
- 00:41:13because DNA is double helix structure.
- 00:41:17You can see each of the bases in here,
- 00:41:21all with different colors,
- 00:41:23the bases are A T C and G,
- 00:41:26and they go together in that format,
- 00:41:28A always bonds with T, C always bonds with G.
- 00:41:32This is to do with the number of connections they can make,
- 00:41:36so you're always going to get A bonding with T,
- 00:41:39and C bonding with G,
- 00:41:41it has a sugar phosphate backbone.
- 00:41:48And there are two of those,
- 00:41:49these that go up the side,
- 00:41:51around the DNA.
- 00:41:56Two strands that can break apart down
- 00:41:58the middle when the DNA wants to replicate.
- 00:42:03A section of DNA such as this can be called a gene,
- 00:42:07and then genes with the information
- 00:42:09for making amino acids and proteins which
- 00:42:11are the building blocks of you and me.
- 00:42:18Sections of DNA can be red,
- 00:42:21so three bases of DNA can be read,
- 00:42:25and turned into an amino acid.
- 00:42:28These amino acids can then build altogether
- 00:42:31to make the gene.
- 00:42:39Alcohols have an -O-H functional group,
- 00:42:43and they end in ol.
- 00:42:45So one with the one carbon is going to be methanol,
- 00:42:50with two carbons,
- 00:42:51ethanol,
- 00:42:53with three carbons,
- 00:42:57propanol,
- 00:42:58with four carbons,
- 00:43:01butanol,
- 00:43:03when we draw our alcohols,
- 00:43:05we need to put -O-H groups on here,
- 00:43:08and we need to remember make sure everything
- 00:43:10has the right number of bonds,
- 00:43:11hydrogen is only ever going to make one bond,
- 00:43:13carbon makes four bonds,
- 00:43:15oxygen makes two bonds.
- 00:43:20Organic chemistry is a very natural place
- 00:43:21for them to stick nasty questions in,
- 00:43:23and this is one of the nasty questions they could sneak in.
- 00:43:27Propan-1-ol has our alcohol group right on the end,
- 00:43:32butan-1-ol has a alcohol group right on the end,
- 00:43:37propan-2-ol has it in the middle,
- 00:43:39here is our alcohol group up here,
- 00:43:41and Butan-2-ol has it in the middle here,
- 00:43:45learn these and recognize them.
- 00:43:49Alcohol can be used for drinking,
- 00:43:50or as a solvent,
- 00:43:52when you react it with sodium it's going to fizz,
- 00:43:54when you react with oxygen it's going to burn,
- 00:43:55it's just a combustion reaction,
- 00:43:57when you reacted with water it's going to dissolve.
- 00:44:01Another way of producing alcohol is fermentation,
- 00:44:04this is where we take sugar and mix it with yeast,
- 00:44:06keep it nice and warm and we're going to get ethanol
- 00:44:09which you can use for alcohol,
- 00:44:10or carbon dioxide which makes the bubbles in bread.
- 00:44:14Exactly the same process beer making and breadmaking.
- 00:44:19If you want to measure the energy released
- 00:44:21by burning alcohols,
- 00:44:22and you can always compare different types
- 00:44:24of alcohol with this,
- 00:44:25you need unknown volume of alcohol,
- 00:44:27you can weigh this on the scales,
- 00:44:29burn it use it to heat a known volume of water,
- 00:44:32and measure the temperature change.
- 00:44:34We can then work out the energy by using
- 00:44:36the mass times temperature change times
- 00:44:38specific heat capacity of water.
- 00:44:43Carboxylic acids have this as a function group.
- 00:44:48Something with one carbon is methanoic acid,
- 00:44:54two carbons is ethanoic acid.
- 00:45:00Three carbons propanoic acid.
- 00:45:07Four carbons butanoic acid.
- 00:45:14Methanoic acid one carbon making four bonds,
- 00:45:17double bonded to oxygen and an alcohol group,
- 00:45:20ethanoic acid propanoic acid and butanoic acid
- 00:45:24you need to be able to recognize and draw these.
- 00:45:29You use carbocyclic acid,
- 00:45:30much more than you recognize,
- 00:45:32because ethanoic acid is vinegar,
- 00:45:34it is an acid,
- 00:45:35so if you react it with any carbonate,
- 00:45:37You're going to get your standard acid carbonate
- 00:45:39reaction and it's going to fizz,
- 00:45:40and if you react it with alcohol you
- 00:45:41are going to make Esther.
- 00:45:45If you react an alcohol with a carboxylic acid
- 00:45:47you're going to get an Esther,
- 00:45:49for example if you react ethanol with ethanoic
- 00:45:50acid you're going to get ethyl ethanoale and water.
- 00:45:56Nanotechnology is absolutely fascinating,
- 00:45:59it is taking atoms and rearranging them
- 00:46:01into specific locations and specific sizes
- 00:46:06so that we can use it,
- 00:46:08it is much much smaller than technology,
- 00:46:10it is very small.
- 00:46:15But it is made up of lots of different atoms,
- 00:46:19now the potentials for this are massive,
- 00:46:21because as we get smaller we are increasing
- 00:46:24the surface area.
- 00:46:30And when we get the small things have very
- 00:46:31very different properties,
- 00:46:33things look see-through,
- 00:46:34things are flexible,
- 00:46:35things start to behave very differently than
- 00:46:37they would if they were much, much larger.
- 00:46:42The potential for this is massive,
- 00:46:44communication and drug delivery,
- 00:46:45personalized medicine,
- 00:46:47but people are wary about this because
- 00:46:48it is a new technology.
- 00:46:52The majority of glass we use is made up of
- 00:46:53a silicon dioxide.
- 00:47:01Ceramics such as clay ceramics are a mixture
- 00:47:03of silicon dioxide and aluminum oxide.
- 00:47:17Well done for making it to the end of this video,
- 00:47:18you are all absolute superstars,
- 00:47:22all the best in your exams I am keeping all
- 00:47:24of my fingers crossed for you.
- 00:47:36(upbeat music)
- LXL chemistry
- periodic table
- reactivity series
- displacement reactions
- rates of reaction
- exothermic
- endothermic
- hydrocarbons
- global warming
- nanotechnology